| Schauspieler | Rolle | Synchronsprecher | ||
| Yuuko Miyamura | Asuka Langley Shikinami | Julia Ziffer Julia Ziffer | ||
| Fumihiko Tachiki | Gendou Ikari | Erich Räuker Erich Räuker | ||
| Anri Katsu | Hideki Tama | Matthias von Stegmann | ||
| Junko Iwao | Hikari Suzuhara | Ilona Otto (Brokowski) Ilona Otto (Brokowski) | ||
| Akira Ishida | Kaworu Nagisa | Robin Kahnmeyer Robin Kahnmeyer | ||
| Tetsuya Iwanaga | Kensuke Aida | Gerrit Schmidt-Foß Gerrit Schmidt-Foß | ||
| Akio Ootsuka | Kouji Takao | Tilo Schmitz Tilo Schmitz | ||
| Motomu Kiyokawa | Kouzou Fuyutsuki | Uli Krohm Uli Krohm | ||
| Hiro Yuuki | Makoto Hyuuga | Frank Leo Schröder Frank Leo Schröder | ||
| Maaya Sakamoto | Mari Illustrious Makinami | Lea Kalbhenn Lea Kalbhenn | ||
| Miki Nagasawa | Maya Ibuki | Maria Koschny Maria Koschny | ||
| Mariya Ise | Midori Kitakami | Sonja Spuhl Sonja Spuhl | ||
| Kotono Mitsuishi | Misato Katsuragi | Julia Kaufmann Julia Kaufmann | ||
| Megumi Hayashibara | Rei Ayanami | Marie Bierstedt Marie Bierstedt | ||
| Yuriko Yamaguchi | Ritsuko Akagi | Peggy Sander Peggy Sander | ||
| Kouichi Yamadera | Ryouji Kaji | Marcel Collé | ||
| Kouki Uchiyama | Ryouji Kaji (Jugendlicher) | Patrick Baehr Patrick Baehr | ||
| Miyuki Sawashiro | Sakura Suzuhara | Melinda Rachfahl Melinda Rachfahl | ||
| Takehito Koyasu | Shigeru Aoba | Rainer Fritzsche Rainer Fritzsche | ||
| Megumi Ogata | Shinji Ikari | Hannes Maurer | ||
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